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1 article(s) from Moriones, Paula

Fiber optic sensors based on hybrid phenyl-silica xerogel films to detect n-hexane: determination of the isosteric enthalpy of adsorption

Jesús C. Echeverría,
Ignacio Calleja,
Paula Moriones and
Julián J. Garrido

Beilstein J. Nanotechnol. 2017, 8, 475–484, doi:10.3762/bjnano.8.51

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Figure 1: Infrared spectra of xerogels in two wavenumber ranges: (a) 4000–2750 cm⁻¹ and (b) 1600–400 cm⁻¹.

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Figure 2: X-ray diffraction patterns of the xerogels synthesized from PhTEOS/TEOS mixtures with 30% (Ph30), 4...

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Figure 3: Adsorption–desorption isotherms of N₂ at 77 K.

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Figure 4: (a) Intensity of the reflected light by sensing elements Ph30, Ph40, and Ph50 at 298 K under vacuum...

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Figure 5: Conditioning of the sensing element Ph40 in the presence of n-hexane at 323 K: (a) first and (b) se...

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Figure 6: Detail of the variation of pressure and the response of the Ph40 sensing element in the presence of...

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Figure 7: Time–response curves for three sensing elements in the presence of n-hexane at 298 K: (a) Ph30, (b)...

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Figure 8: Time–response curves for the sensing element Ph40 in the presence of n-hexane: (a) 288 K, (b) 298 K...

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Figure 9: Calibration curves for the Ph40 sensing element in the presence of n-hexane at 288, 298, 308, and 3...

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Figure 10: Clausius–Clapeyron plots, ln C plotted against the reciprocal absolute temperature for the response...

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Figure 11: Isosteric adsorption enthalpy. Dashed line: the condensation enthalpy of n-hexane on a flat liquid ...

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Published 21 Feb 2017

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